The Journal of organic chemistry

Intramolecular alkyne carbomercuration by allylic silanes: A new carbon-carbon bond-forming reaction

H Huang, CJ Forsyth

Index: Huang, He; Forsyth, Craig J. Journal of Organic Chemistry, 1997 , vol. 62, # 24 p. 8595 - 8596

Full Text: HTML

Citation Number: 20

Abstract

Intramolecular alkyne carbomercuration (IAC) of alkynyl-tethered enol silanes is a mild, versatile, and highyielding method for the formation of cyclic products bearing a mercuric- functionalized exocyclic alkene β to a carbonyl group. 1 The vinyl mercurial moiety of the

~36%

~99%

Convenient synthesis of non-conjugated alkynyl ketones from ...

[Boltukhina, Ekaterina V.; Sheshenev, Andrey E.; Lyapkalo, Ilya M. Tetrahedron, 2011 , vol. 67, # 30 p. 5382 - 5388]

Development of Zn–ProPhenol??Catalyzed Asymmetric Alkyne Add...

[Trost, Barry M.; Bartlett, Mark J.; Weiss, Andrew H.; Vonwangelin, Axel Jacobi; Chan, Vincent S. Chemistry - A European Journal, 2012 , vol. 18, # 51 p. 16498 - 16509]

Solvents of low nucleophilicity. XII. Triple-bond participat...

[Peterson,P.E.; Kamat,R.J. Journal of the American Chemical Society, 1969 , vol. 91, p. 4521 - 4527]

A New Cyclization. 2-Methylenecyclopentanols by the Chemical...

[Stork,G. et al. Journal of the American Chemical Society, 1965 , vol. 87, p. 1148 - 1149]