e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Driven Evolution of a Constitutional Dynamic Library of Molecular Helices Toward the Selective Generation of [2× 2] Gridlike Arrays under the Pressure of Metal Ion …

N Giuseppone, JL Schmitt, JM Lehn

Index: Giuseppone, Nicolas; Schmitt, Jean-Louis; Lehn, Jean-Marie Journal of the American Chemical Society, 2006 , vol. 128, # 51 p. 16748 - 16763

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Citation Number: 63

Abstract

Constitutional dynamics, self-assembly, and helical-folding control are brought together in the efficient Sc (OTf) 3/microwave-catalyzed transimination of helical oligohydrazone strands, yielding highly diverse dynamic libraries of interconverting constituents through assembly, dissociation, and exchange of components. The transimination-type mechanism of the ScIII-promoted exchange, as well as its regioselectivity, occurring only at the ...

4-(methoxymethyl)-2-phenyl-6-pyridin-2-ylpyrimidine Structure

4-(methoxymethy...

~%

(2-phenyl-6-pyridin-2-ylpyrimidin-4-yl)methanol Structure

(2-phenyl-6-pyr...

2-(Trimethylstannyl)pyridine Structure

2-(Trimethylsta...

~%

(2-phenyl-6-pyridin-2-ylpyrimidin-4-yl)methanol Structure

(2-phenyl-6-pyr...

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~%

(2-phenyl-6-pyridin-2-ylpyrimidin-4-yl)methanol Structure

(2-phenyl-6-pyr...

4-(methoxymethyl)-2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidine Structure

4-(methoxymethy...

~%

[2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidin-4-yl]methanol Structure

[2-phenyl-6-(6-...

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~%

[2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidin-4-yl]methanol Structure

[2-phenyl-6-(6-...

[2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidin-4-yl]methanol Structure

[2-phenyl-6-(6-...

~%

2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidine-4-carbaldehyde Structure

2-phenyl-6-(6-p...

4-(methoxymethyl)-2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidine Structure

4-(methoxymethy...

~%

2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidine-4-carbaldehyde Structure

2-phenyl-6-(6-p...

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~%

2-phenyl-6-(6-pyridin-2-ylpyridin-2-yl)pyrimidine-4-carbaldehyde Structure

2-phenyl-6-(6-p...

(2-phenyl-6-pyridin-2-ylpyrimidin-4-yl)methanol Structure

(2-phenyl-6-pyr...

~%

2-phenyl-6-pyridin-2-ylpyrimidine-4-carbaldehyde Structure

2-phenyl-6-pyri...

4-(methoxymethyl)-2-phenyl-6-pyridin-2-ylpyrimidine Structure

4-(methoxymethy...

~%

2-phenyl-6-pyridin-2-ylpyrimidine-4-carbaldehyde Structure

2-phenyl-6-pyri...

2-(Trimethylstannyl)pyridine Structure

2-(Trimethylsta...

~%

2-phenyl-6-pyridin-2-ylpyrimidine-4-carbaldehyde Structure

2-phenyl-6-pyri...

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~%

2-phenyl-6-pyridin-2-ylpyrimidine-4-carbaldehyde Structure

2-phenyl-6-pyri...

monomethylhydrazine Structure

monomethylhydrazine

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~80%

1-[6-(methoxymethyl)-2-phenylpyrimidin-4-yl]-1-methylhydrazine Structure

1-[6-(methoxyme...

monomethylhydrazine Structure

monomethylhydrazine

(6-Chloro-2-phenylpyrimidin-4-yl)methanol Structure

(6-Chloro-2-phe...

~72%

[6-[amino(methyl)amino]-2-phenylpyrimidin-4-yl]methanol Structure

[6-[amino(methy...

2-(Trimethylstannyl)pyridine Structure

2-(Trimethylsta...

4-chloro-6-(methoxymethyl)-2-phenylpyrimidine Structure

4-chloro-6-(met...

~70%

4-(methoxymethyl)-2-phenyl-6-pyridin-2-ylpyrimidine Structure

4-(methoxymethy...