Cationic cyclocodimerization. 3. Syntheses of [3.3] paracyclo (1, 4) naphthalenophane and [3.3](1, 4) naphthalenophane derivatives. Stereoselectivity governed by the …

J Nishimura, N Yamada, T Okuda, Y Mukai…

Index: Nishimura, Jun; Yamada, Noriyuki; Okuda, Tomohisa; Mukai, Yoshihiko; Hashiba, Hidetoshi; Oku, Akira Journal of Organic Chemistry, 1985 , vol. 50, # 6 p. 836 - 841

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Citation Number: 5

Abstract

The cationic cyclocodimerization of l-(4-vinylnaphthyl)-3-(p-vinylphenyl) propane and 1, 3- bis (4-vinylnaphthy1) propane with 2-phenylpropene, indene, 1, l-diphenylethylene, and styrene gave [3.3] paracyclo (1, 4)-naphthalenophanes and [3.3](1, 4) naphthalenophanes, respectively, in 11.5-53.6% yields. From the structures of carbophanes produced, it is concluded that the stereoselectivity shown in the cationic cyclocodimerization can, be ...