… , thermally stable, sublimable aminoboranes B (NHAr) X 2 (X= Cl, F, or NH 2); X-ray crystal structure of bis (amino)(2, 4, 6-tri-t-butylphenylamino) borane, B (NH 2) 2 ( …

PB Hitchcock, HA Jasim, MF Lappert…

Index: Hitchcock, Peter B.; Jasim, Hatam A.; Lappert, Michael F.; Williams, Hugh D. Journal of the Chemical Society, Chemical Communications, 1984 , # 10 p. 662 - 664

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Citation Number: 8

Abstract

The sterically demanding 2, 4, 6-tri-t-butylamido lignad ([[N with combining macron]] HAr) confers unexpected thermal stability on the title boranes B (NHAr) X [X= Cl,(); F,(); or NH,()], each of which is sublimable without elimination of HX; the difluoroborane () has significant BN double-bond character as is evident from magnetically distin