Metathesis studies to cyclic enol phosphonamidates

…, MD McReynolds, CE Schroeder, PR Hanson

Index: Sieck, Stephen R.; McReynolds, Matthew D.; Schroeder, Chad E.; Hanson, Paul R. Journal of Organometallic Chemistry, 2006 , vol. 691, # 24-25 p. 5307 - 5311

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Citation Number: 10

Abstract

The development of cyclic, six membered enol phosphonamidates utilizing the ring-closing metathesis (RCM) reaction is discussed. Phosphonamidic monochloridates are generated and further functionalized to an array of acyclic, enol phosphonamidates. Subsequent metathesis affords both desired RCM product and corresponding cross metathesis (CM) dimer. Efforts to optimize formation of desired RCM product, while minimizing CM products ...