Synthesis of (Z)??N??Alkenylazoles and Pyrroloisoquinolines from α??N??Azoleketones through Pd??Catalyzed Tosylhydrazone Cross??Couplings

L Florentino, F Aznar, C Valdés

Index: Florentino, Lucia; Aznar, Fernando; Valdes, Carlos Chemistry - A European Journal, 2013 , vol. 19, # 32 p. 10506 - 10510

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Citation Number: 14

Abstract

In recent years, the chemistry of tosylhydrazones has gained increasing attention as a result of the development of new metal-catalyzed and metal-free cross-coupling reactions.[1] In particular, the Pd-catalyzed cross-coupling of tosylhydrazones and organic halides represents a very efficient method to transform a carbonyl compound into the nucleophilic component of a CÀC bond forming cross-coupling reaction.[2] Currently, this ...