Tetrahedron letters

Electronic effects on carbon-chlorine bonds

EW Warnhoff, A Nakamura

Index: Warnhoff, E. W.; Nakamura, Akira Tetrahedron Letters, 1984 , vol. 25, # 5 p. 503 - 506

Full Text: HTML

Citation Number: 2

Abstract

For the first time a reaction has been found to study electronic effects on CC1 bonds in an equilibrium situation. The reaction, the α α α′ rearrangement of α-chlorodibenzyl ketones, correlates well with the difference in Taft σ° values with ϱ +0.75. ... Although in some cases the reaction mixture

 Related Synthetic Route
P-Tolyacetonitrile Structure

2947-61-7

P-Tolyacetonitrile

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

α-(p-Methylphenyl)-γ-phenyl-acetacetonitril Structure

35741-46-9

α-(p-Methylphen...

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

Ethyl phenylacetate Structure

101-97-3

Ethyl phenylacetate

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

1-(P-TOLYL)-3-PHENYL-2-PROPANONE Structure

35730-02-0

1-(P-TOLYL)-3-P...

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

P-Tolyacetonitrile Structure

2947-61-7

P-Tolyacetonitrile

~%

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

α-(p-Methylphenyl)-γ-phenyl-acetacetonitril Structure

35741-46-9

α-(p-Methylphen...

~%

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

Ethyl phenylacetate Structure

101-97-3

Ethyl phenylacetate

~%

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

1-(P-TOLYL)-3-PHENYL-2-PROPANONE Structure

35730-02-0

1-(P-TOLYL)-3-P...

~%

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

1-chloro-3-(4-methylphenyl)-1-phenylpropan-2-one Structure

90176-71-9

1-chloro-3-(4-m...

~%

1-chloro-1-(4-methylphenyl)-3-phenylpropan-2-one Structure

90176-72-0

1-chloro-1-(4-m...

Ethyl (4-methylphenyl)acetate Structure

14062-19-2

Ethyl (4-methyl...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

α-(p-Chlorphenyl)-γ-(p-methylphenyl)-acetacetonitril Structure

35730-01-9

α-(p-Chlorpheny...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

4-Chlorobenzyl cyanide Structure

140-53-4

4-Chlorobenzyl ...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

1-p-Methylphenyl-3-p-chlorphenyl-2-propanon Structure

35730-04-2

1-p-Methylpheny...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

Ethyl (4-methylphenyl)acetate Structure

14062-19-2

Ethyl (4-methyl...

~%

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

α-(p-Chlorphenyl)-γ-(p-methylphenyl)-acetacetonitril Structure

35730-01-9

α-(p-Chlorpheny...

~%

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

4-Chlorobenzyl cyanide Structure

140-53-4

4-Chlorobenzyl ...

~%

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

1-p-Methylphenyl-3-p-chlorphenyl-2-propanon Structure

35730-04-2

1-p-Methylpheny...

~%

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

1-chloro-1-(4-chlorophenyl)-3-(4-methylphenyl)propan-2-one Structure

90176-73-1

1-chloro-1-(4-c...

~%

1-chloro-3-(4-chlorophenyl)-1-(4-methylphenyl)propan-2-one Structure

90176-74-2

1-chloro-3-(4-c...

Ethyl (4-methylphenyl)acetate Structure

14062-19-2

Ethyl (4-methyl...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

3-oxo-4-(p-tolyl)-2-(3-(trifluoromethyl)phenyl)butanenitrile Structure

344874-67-5

3-oxo-4-(p-toly...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

3-(Trifluoromethyl)benzyl cyanide Structure

2338-76-3

3-(Trifluoromet...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

1-(p-tolyl)-3-(3-(trifluoromethyl)phenyl)propan-2-one Structure

344866-75-7

1-(p-tolyl)-3-(...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

Ethyl (4-methylphenyl)acetate Structure

14062-19-2

Ethyl (4-methyl...

~%

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

3-oxo-4-(p-tolyl)-2-(3-(trifluoromethyl)phenyl)butanenitrile Structure

344874-67-5

3-oxo-4-(p-toly...

~%

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

3-(Trifluoromethyl)benzyl cyanide Structure

2338-76-3

3-(Trifluoromet...

~%

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

1-(p-tolyl)-3-(3-(trifluoromethyl)phenyl)propan-2-one Structure

344866-75-7

1-(p-tolyl)-3-(...

~%

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

1-chloro-3-(4-methylphenyl)-1-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-75-3

1-chloro-3-(4-m...

~%

1-chloro-1-(4-methylphenyl)-3-[3-(trifluoromethyl)phenyl]propan-2-one Structure

90176-76-4

1-chloro-1-(4-m...

α-(p-Methylphenyl)-γ-phenyl-acetacetonitril Structure

35741-46-9

α-(p-Methylphen...

~%

1-(P-TOLYL)-3-PHENYL-2-PROPANONE Structure

35730-02-0

1-(P-TOLYL)-3-P...

P-Tolyacetonitrile Structure

2947-61-7

P-Tolyacetonitrile

~%

1-(P-TOLYL)-3-PHENYL-2-PROPANONE Structure

35730-02-0

1-(P-TOLYL)-3-P...

Ethyl phenylacetate Structure

101-97-3

Ethyl phenylacetate

~%

1-(P-TOLYL)-3-PHENYL-2-PROPANONE Structure

35730-02-0

1-(P-TOLYL)-3-P...

1-methyl-4-(2-nitroethyl)benzene Structure

72538-33-1

1-methyl-4-(2-n...

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

4-Nitrobenzaldehyde Structure

555-16-8

4-Nitrobenzaldehyde

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

1-methyl-4-(2-nitro-3-(4-nitrophenyl)propyl)benzene Structure

344871-78-9

1-methyl-4-(2-n...

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

1-(4-nitrophenyl)-3-(p-tolyl)propan-2-one Structure

344871-85-8

1-(4-nitropheny...

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

1-methyl-4-(2-nitroethyl)benzene Structure

72538-33-1

1-methyl-4-(2-n...

~%

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

4-Nitrobenzaldehyde Structure

555-16-8

4-Nitrobenzaldehyde

~%

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

1-methyl-4-(2-nitro-3-(4-nitrophenyl)propyl)benzene Structure

344871-78-9

1-methyl-4-(2-n...

~%

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

1-(4-nitrophenyl)-3-(p-tolyl)propan-2-one Structure

344871-85-8

1-(4-nitropheny...

~%

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...

1-chloro-3-(4-methylphenyl)-1-(4-nitrophenyl)propan-2-one Structure

90176-77-5

1-chloro-3-(4-m...

~%

1-chloro-1-(4-methylphenyl)-3-(4-nitrophenyl)propan-2-one Structure

90176-78-6

1-chloro-1-(4-m...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved