Catalysis Communications 2018-04-01

Laccase-TEMPO as an efficient catalyst system for metal- and halogen-free aerobic oxidation of thioethers to sulfoxides in aqueous media at ambient conditions

Amin Rostami, Behnaz Mohammadi, Zahra Shokri, Shaghayegh Saadati

Index: 10.1016/j.catcom.2018.03.032

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Abstract

We present for the first time an eco-friendly procedure for the aerobic oxidation of thioethers to sulfoxides using laccase-TEMPO catalyst system. This catalyst system allows for simpler (easy work-up) and greener methodologies (room temperature, phosphate buffer) while keeping high reaction yields and selectivity. This work is superior to others due to free from any transition metal and halide co-catalysts.