e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Tetrahedron letters

New stereocontrolled approach to some insect pheromones via silicon-directed beckmann fragmentation

H Nishiyama, K Sakuta, K Itoh

Index: Nishiyama, Hisao; Sakuta, Koji; Itoh, Kenji Tetrahedron Letters, 1984 , vol. 25, # 2 p. 223 - 226

Full Text: HTML

Citation Number: 30

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The major components of sex pheromones of potato tuberworm moth and Douglas fir tussock moth have been synthesized via the regio- and stereo-controlled Beckmann fragmentation assisted by trimethylsilyl group. ... No addition of n-Bu 3 SnCl gave a mixture of complicated ...

1-bromo-2-octyne Structure

1-bromo-2-octyne

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

(2S,3S)-2-((Z)-oct-2-en-1-yl)-3-(trimethylsilyl)cyclopentan-1-one Structure

(2S,3S)-2-((Z)-...

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

(2R,3R)-2-oct-2-ynyl-3-trimethylsilylcyclopentan-1-one Structure

(2R,3R)-2-oct-2...

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

1-Bromopentane Structure

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

2-Octyn-1-ol Structure

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

(2R,3R)-2-((Z)-oct-2-en-1-yl)-3-(trimethylsilyl)cyclopentan-1-one oxime Structure

(2R,3R)-2-((Z)-...

~%

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

1-Bromopentane Structure

~%

1-bromo-2-octyne Structure

1-bromo-2-octyne

Cyclohexanone, 2-pentyl-3-(trimethylsilyl)-, cis Structure

Cyclohexanone, ...

~%

undec-5-enenitrile Structure

undec-5-enenitrile

2-pentylcyclohex-2-en-1-one Structure

2-pentylcyclohe...

~%

undec-5-enenitrile Structure

undec-5-enenitrile

1-bromo-2-octyne Structure

1-bromo-2-octyne

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

(2S,3S)-2-((Z)-oct-2-en-1-yl)-3-(trimethylsilyl)cyclopentan-1-one Structure

(2S,3S)-2-((Z)-...

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

(2R,3R)-2-oct-2-ynyl-3-trimethylsilylcyclopentan-1-one Structure

(2R,3R)-2-oct-2...

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

(2R,3R,Z)-2-((Z)-oct-2-en-1-yl)-3-(trimethylsilyl)cyclopentan-1-one O-acetyl oxime Structure

(2R,3R,Z)-2-((Z...

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

1-Bromopentane Structure

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

Ethanoic anhydride Structure

Ethanoic anhydride

trideca-4,7-dienenitrile Structure

trideca-4,7-die...

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...

(2R,3R)-2-((Z)-oct-2-en-1-yl)-3-(trimethylsilyl)cyclopentan-1-one oxime Structure

(2R,3R)-2-((Z)-...

~%

(Z,E)-trideca-4,7-dien-1-yl acetate Structure

(Z,E)-trideca-4...