Synthesis of dialkylamines via the reaction of organoboranes with N-chloroalkylamines

GW Kabalka, GW McCollum…

Index: Kabalka, George W.; McCollum Gary W.; Kunda, Sastry A. Journal of Organic Chemistry, 1984 , vol. 49, p. 1656 - 1658

Full Text: HTML

Citation Number: 18

Abstract

R3B+ R'NHCl-RR'NH alkylamines via the reaction of trialkylboranes with organic azide^.^ Our results are summarized in Tables I and 11. The reaction is analogous to the reaction of chloramine with organoboranes and presumably occurs via an anionotropic migration of an alkyl group from boron to nitrogen.