European Journal of Organic Chemistry 2018-03-30

Fluorine‐Containing Functionalized Cyclopentene Scaffolds Through Ring Contraction and Deoxofluorination of Various Substituted Cyclohexenes

Attila Márió Remete; Melinda Nonn; Santos Fustero; Matti Haukka; Ferenc Fülöp; Loránd Kiss

Index: 10.1002/ejoc.201800057

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Abstract

The fluorination of some highly‐functionalized cyclopentene derivatives, obtained from various substituted cyclohexenes through a ring‐opening/ring‐contraction procedure, has been investigated. The transformations were found to be highly substrate dependent, and led to the formation of various functionalized alicyclic compounds or heterocycles containing allyl difluoride or vinyl fluoride moieties.