Tetrahedron Letters

Insertion of alkanal carbonyl and 1, 3-diene units between Si Si bonds of trisilanes. Synthesis of novel silicon-containing materials

T Hiyama, M Obayashi

Index: Hiyama, Tamejiro; Obayashi, Michio Tetrahedron Letters, 1983 , vol. 24, # 38 p. 4109 - 4112

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Citation Number: 19

Abstract

Octamethyltrisilane/tetrabutylammonium fluoride reagent allows us to insert A=B (eg alkanals and 1,3-dienes) between the SiSi bonds to produce Si-AB-Si-BA-Si structure in one step or Si-AB-Si-B′-A′-Si step by step. ... The new compound gave correct elemental analytic data. ... Mp 45–46.5°C; IR (KBr) 3350, 1470, 1380, 1250, 940, 840, 780 cm −1 ; 1 H NMR (CCl 4 ) ° −0.10–0.02 0.02 (4s, 6 H), 0.84 (t, J = 6 Hz, 6 H), 1.00–1.70 (m, 36 H), 3.25–3.45 (m, ...