Tetrahedron letters

Dienophilic anthracenes: formation of novel triptycenes via thermal and photochemical intramolecular diels-alder reactions of dianthrylethanes

HD Becker, K Andersson

Index: Becker, Hans-Dieter; Andersson, Kjell Tetrahedron Letters, 1983 , vol. 24, # 31 p. 3273 - 3276

Full Text: HTML

Citation Number: 13

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... 1,2-Di(9-anthryl) ethanes, accessible by thermolysis of lepidopterenes, undergo thermal and photochemical intramolecular Diels-Alder reactions to give 1,2-dihydroanthracenes whose aromatization leads to novel derivatives of triptycene. ... A minor by-product of the thermolysis of in the ...

 Related Synthetic Route
Dibenzyllepidopterene Structure

74998-96-2

Dibenzyllepidop...

~81%

9-ethyl-10-[2-(10-ethylanthracen-9-yl)ethyl]anthracene Structure

88087-74-5

9-ethyl-10-[2-(...

5,6,11,12-tetrahydro-4b,12<1',2'>:6,10b<1'',2''>-dibenzenochrysene Structure

55614-27-2

5,6,11,12-tetra...

~84%

9-(2-anthracen-9-ylethyl)anthracene Structure

4709-79-9

9-(2-anthracen-...

6,12-dibenzyl-5,6,11,12-tetrahydro-4b,12:6,10b-bis([1,2]benzeno)chrysene Structure

74998-97-3

6,12-dibenzyl-5...

~88%

9-benzyl-10-[2-(10-benzylanthracen-9-yl)ethyl]anthracene Structure

88087-75-6

9-benzyl-10-[2-...

METHYLMAGNESIUM IODIDE Structure

917-64-6

METHYLMAGNESIUM...

1,5-DICHLOROANTHRAQUINONE Structure

82-46-2

1,5-DICHLOROANT...

~70%

1,5-dichloro-10-hydroxy-10-methylanthracen-9-one Structure

88087-77-8

1,5-dichloro-10...

(4bS,6S,10bS,12S)-6,12-bis(naphthalen-1-ylmethyl)-5,6,11,12-tetrahydro-4b,12:6,10b-bis([1,2]benzeno)chrysene Structure

77999-00-9

(4bS,6S,10bS,12...

~82%

9-(naphthalen-1-ylmethyl)-10-[2-[10-(naphthalen-1-ylmethyl)anthracen-9-yl]ethyl]anthracene Structure

88121-52-2

9-(naphthalen-1...

Dimethyllepidopterene Structure

55657-77-7

Dimethyllepidop...

~80%

9-methyl-10-[2-(10-methylanthracen-9-yl)ethyl]anthracene Structure

53545-70-3

9-methyl-10-[2-...

1,5-dichloro-10-methylideneanthracen-9-one Structure

88087-78-9

1,5-dichloro-10...

~47%

1,5-dichloro-9-[2-(1,5-dichloroanthracen-9-yl)ethyl]anthracene Structure

88087-79-0

1,5-dichloro-9-...

1,5-dichloro-10-hydroxy-10-methylanthracen-9-one Structure

88087-77-8

1,5-dichloro-10...

~%

1,5-dichloro-9-[2-(1,5-dichloroanthracen-9-yl)ethyl]anthracene Structure

88087-79-0

1,5-dichloro-9-...

1,5-DICHLOROANTHRAQUINONE Structure

82-46-2

1,5-DICHLOROANT...

~%

1,5-dichloro-9-[2-(1,5-dichloroanthracen-9-yl)ethyl]anthracene Structure

88087-79-0

1,5-dichloro-9-...

N/A Structure

74998-98-4

N/A

~82%

9-phenyl-10-[2-(10-phenylanthracen-9-yl)ethyl]anthracene Structure

71582-26-8

9-phenyl-10-[2-...

1,5-dichloro-10-hydroxy-10-methylanthracen-9-one Structure

88087-77-8

1,5-dichloro-10...

~82%

1,5-dichloro-10-methylideneanthracen-9-one Structure

88087-78-9

1,5-dichloro-10...

1,5-DICHLOROANTHRAQUINONE Structure

82-46-2

1,5-DICHLOROANT...

~%

1,5-dichloro-10-methylideneanthracen-9-one Structure

88087-78-9

1,5-dichloro-10...


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