Crystallographic characterization of difluoropropargyl indium bromide, a reactive fluoroorganometallic reagent

…, MS Mashuta, GB Hammond

Index: Xu, Bo; Mashuta, Mark S.; Hammond, Gerald B. Angewandte Chemie - International Edition, 2006 , vol. 45, # 43 p. 7265 - 7267

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Citation Number: 27

Abstract

7265 Angew. Chem. Int. Ed. 2006, 45, 7265–7267 2006 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim gen exchange or transmetalation—and their subsequent reaction with electrophiles continue to be actively pursued.[2] Initially, an indium sesquihalide (R3In2X3) was regarded as a synthetic intermediate.[3] On the basis of recent NMR data, researchers have proposed that indium (I) and indium (III) complexes, or a combination thereof, could ...