ChemElectroChem 2018-02-21

Probing Electron Transfer in the Manganese–Oxide‐Forming MnxEFG Protein Complex using Fourier‐Transformed AC Voltammetry: Understanding the Oxidative Priming Effect

Lizhi Tao; Alexandr N. Simonov; Christine A. Romano; Cristina N. Butterfield; Bradley M. Tebo; Alan M. Bond; Leone Spiccia; Lisandra L. Martin; William H. Casey

Index: 10.1002/celc.201800219

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Abstract

The Cover Feature illustrates the manganese oxidizing MnxEFG protein complex immobilized on an electrode surface and probed by Fourier‐transformed alternating current voltammetry. This analysis enables the detection of electron transfer of the copper co‐factor, and correlates the electron‐transfer rate in this cofactor with the enzymatic activity of the MnxEFG complex. More information can be found in the Article by L. Tao et al.