Abstract New chromenes annulated with different six-membered azaheterocycles were prepared, ie, the 3H-pyra-no [3, 2-f] quinolines 9/10 and 14, the 8H-pyrano [2, 3-h] isoquinoline 11, the 8H-pyrano [3, 2-f] quinazolme 12, the 8-H-pyrano [3, 2-f] quinoxaline 13, and the 2H-pyrano [2, 3-f] isoquinoline 15. The synthesis was achieved using conveniently substituted α, β-unsaturated aldehydes and organotitanium intermediates arising from ...