Nitration of 2-cyclohexenone derivatives and some reactions of the products.

的場勝英， 森田多賀史， 山崎高應

Index: Matoba, Katsuhide; Morita, Takashi; Yamazaki, Takao Chemical & Pharmaceutical Bulletin, 1983 , vol. 31, # 12 p. 4368 - 4375

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Citation Number: 1

Abstract

... Pharm. BU11.J 31(12)4368—4375(l983) Nitration of 2-Cyclohexenone Derivatives and Some Reactions of the Products” KATSUHIDE MATOBA,* TAKASHI MORITA, and TAKAO YAMAZAKI Faculty Of ... The chemical shifts and coupling constants (J) are given in 6 and Hz. ...

 Related Synthetic Route
diazomethane Structure

186581-53-3

diazomethane

5,5-dimethyl-2-nitrocyclohexa-1,3-dien-1-ol Structure

84903-28-6

5,5-dimethyl-2-...

~37%

2-hydroxyimino-5,5-dimethylcyclohex-3-en-1-one Structure

84903-31-1

2-hydroxyimino-...

3a-hydroxy-5,5-dimethyl-1-oxy-3,3a,4,5-tetrahydro[2,1]benzisoxazole Structure

84903-30-0

3a-hydroxy-5,5-...

5,5-DIMETHYLCYCLOHEX-2-EN-1-ONE Structure

4694-17-1

5,5-DIMETHYLCYC...

~40%

2,6-bis(hydroxyimino)-5,5-dimethylcyclohex-3-en-1-one Structure

90252-94-1

2,6-bis(hydroxy...

2-hydroxyimino-5,5-dimethylcyclohex-3-en-1-one Structure

84903-31-1

2-hydroxyimino-...

5,5-DIMETHYLCYCLOHEX-2-EN-1-ONE Structure

4694-17-1

5,5-DIMETHYLCYC...

~3%

2,6-bis(hydroxyimino)-5,5-dimethylcyclohex-3-en-1-one Structure

90252-94-1

2,6-bis(hydroxy...

2-hydroxyimino-5,5-dimethylcyclohex-3-en-1-one Structure

84903-31-1

2-hydroxyimino-...

(2S,3R)-3,5,5-trimethyl-2-nitrocyclohexan-1-one Structure

74609-82-8

(2S,3R)-3,5,5-t...

Ethanoic anhydride Structure

108-24-7

Ethanoic anhydride

~11%

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

all-trans 3,5,5-trimethyl-2-nitrocyclohexanol Structure

81842-56-0

all-trans 3,5,5...

(2S,3R)-3,5,5-trimethyl-2-nitrocyclohexan-1-one Structure

74609-82-8

(2S,3R)-3,5,5-t...

~11%

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

all-trans 3,5,5-trimethyl-2-nitrocyclohexanol Structure

81842-56-0

all-trans 3,5,5...

Isophorone Structure

78-59-1

Isophorone

~%

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

3,5,5-trimethyl-2-nitrocyclohex-2-en-1-one Structure

84903-29-7

3,5,5-trimethyl...

~%

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

Ethanol Structure

64-17-5

Ethanol

3,5,5-trimethyl-2-nitrocyclohex-2-en-1-one Structure

84903-29-7

3,5,5-trimethyl...

~22%

(2S,3R)-3,5,5-trimethyl-2-nitrocyclohexan-1-one Structure

74609-82-8

(2S,3R)-3,5,5-t...

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

Detail
Isophorone Structure

78-59-1

Isophorone

~%

ethyl 6-acetamido-3,3,5-trimethylhexanoate Structure

90252-98-5

ethyl 6-acetami...

(2S,3R)-3,5,5-trimethyl-2-nitrocyclohexan-1-one Structure

74609-82-8

(2S,3R)-3,5,5-t...

~%

ethyl 6-acetamido-3,3,5-trimethylhexanoate Structure

90252-98-5

ethyl 6-acetami...

3,5,5-trimethyl-2-nitrocyclohex-2-en-1-one Structure

84903-29-7

3,5,5-trimethyl...

~%

ethyl 6-acetamido-3,3,5-trimethylhexanoate Structure

90252-98-5

ethyl 6-acetami...

ethyl 3,3,5-trimethyl-6-nitrohexanoate Structure

90252-97-4

ethyl 3,3,5-tri...

~%

ethyl 6-acetamido-3,3,5-trimethylhexanoate Structure

90252-98-5

ethyl 6-acetami...

Isophorone Structure

78-59-1

Isophorone

~73%

3,5,5-trimethyl-2-nitrocyclohex-2-en-1-one Structure

84903-29-7

3,5,5-trimethyl...


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