Oxidative coupling-type mechanism of N, N-dialkylanilines in solvent-free conditions forming crystal violet derivatives. A clay-mediated and microwave-promoted …

JG López-Cortés, G Penieres-Carrillo…

Index: Lopez-Cortes; Penieres-Carrillo; Ortega-Alfaro; Gutierrez-Perez; Toscano; Alvarez-Toledano Canadian Journal of Chemistry, 2000 , vol. 78, # 10 p. 1299 - 1304

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Citation Number: 15

Abstract

In the clay-mediated reaction of N, N-disubstituted anilines using microwave radiation as an energy source in the absence of solvent, crystal violet and derivatives, diphenylmethanes, and biphenyls were isolated along with intermediates supporting an oxidative coupling-type mechanism. Key words: clay, dyes, microwave radiation, solvent-free reactions.