Hemilabile Thioether Ligands Based on Pyrimidine and/or Pyridine Derivatives that Interconvert between N, S??and N??Coordination in Congested Ruthenium (II) …

…, L Baradello, S Lanza, P Cardiano

Index: Tresoldi, Giuseppe; Baradello, Laura; Lanza, Santo; Cardiano, Paola European Journal of Inorganic Chemistry, 2005 , # 12 p. 2423 - 2435

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Citation Number: 5

Abstract

Abstract The thioether ligands L [L= 2-pyridylmethyl 2'-pyridyl sulfide (L 1), 2-pyridylmethyl 2'- pyrimidyl sulfide (L 2) and 2-pyridylmethyl 2'-(4-methylpyrimidyl) sulfide (L 3)] react with cis- [Ru (N, N-diimine) 2 Cl 2]{diimine= 2, 2'-bipyridine (bipy), di-2-pyrimidyl sulfide (dprs), 2, 2'- bis (5-ethylpyrimidyl) sulfide (5edprs)} to give compounds [Ru (N, N-diimine) 2 L][PF 6] 2 {diimine= bipy, L= L 1 (1), L 2 (2), L 3 (3); diimine= dprs, L= L 1 (4); diimine= 5edprs, L= L ...