Tetrahedron Letters

Solvolysis of 2-m-chlorobenzoyloxy-4-isopropyl-2h-1, 4-thiazin-3-one generation of a stable carbocation

M Hojo, R Masuda, T Ichi, K Yoshinaga, M Yamada

Index: Hojo, M.; Masuda, R.; Ichi, T.; Yoshinaga, K.; Yamada, M. Tetrahedron Letters, 1982 , vol. 23, # 47 p. 4963 - 4964

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Citation Number: 2

Abstract

Abstract The title compound 2b undergoes nucleophilic substition reactions with exclusive aklyl-oxygen bond fission and its rate of solvolysis is highly sensitive toward change in polarity of solvents, as is shown by its highest m-value of all reported so far in logK-logk 0= mY.