Tetrahedron

Action du phenyltetrafluorophosphorane sur les α ou β hydroxy-esters,-cetones,-Nitriles,-ethers, et les nitroalcools. Acces a quelques derives fonctionnels α ou β …

DJ Costa, NE Boutin, JG Riess

Index: Costa,D.J. et al. Tetrahedron, 1974 , vol. 30, p. 3793 - 3797

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Citation Number: 11

Abstract

The reaction of phenyltetrafluorophosphorane with secondary or tertiary α-or β-hydroxy esters, ketones, nitriles, ethers and nitro derivatives has been investigated. The formation of the alkoxyfluorophosphorane 3 has been established in several cases. Good yields of isolated fluoro compounds were obtained with MeCHFCOOEt, MeCHFCH2COOEt and Me2CFCH2NO2. These compounds eliminate HF readily.