Tetrahedron

Diastereoselective synthesis of the model insect antifeedants related to azadiradione and epoxyazadiradione based on intramolecular insertion of α-aryl-α- …

A Fernández-Mateos, GP Coca, JJP Alonso…

Index: Fernandez-Mateos; Pascual Coca; Perez Alonso; Rubio Gonzalez; Simmonds; Blaney Tetrahedron, 1998 , vol. 54, # 49 p. 14989 - 14998

Full Text: HTML

Citation Number: 10

Abstract

A new practical and stereoselective method for the synthesis of the model insect antifeedant CDE fragment of azadiradione and epoxyazadiradione, based on intramolecular insertion of α-aryl-α-diazoketones, has been developed. The procedure can be applied to complex systems. A short SAR study is reported.