On the functionalization of [2.2](1, 4) phenanthrenoparacyclophane

H Hopf, J Hucker, L Ernst

Index: Hopf, Henning; Hucker, Joachim; Ernst, Ludger European Journal of Organic Chemistry, 2007 , # 12 p. 1891 - 1904

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Citation Number: 4

Abstract

Abstract Two routes for preparing functionalized [2.2](1, 4) phenanthrenoparacyclophanes are described: either the parent system 2 is subjected to electrophilic substitution (bromination, Friedel–Crafts acylation, Rieche formylation: preparation of 5, 6, 7, 11 and 12) or the desired substituents are incorporated in the early stages of the synthesis by the preparation of the corresponding functionalized styryl paracyclophanes and their ...