Temperature??dependent rate coefficient measurements for the reaction of bromine atoms with trichloroethene, ethene, acetylene, and tetrachloroethene in air

B Ramacher, JJ Orlando…

Index: Ramacher, Bjoern; Orlando, John J.; Tyndall, Geoffrey S. International Journal of Chemical Kinetics, 2001 , vol. 33, # 3 p. 198 - 211

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Citation Number: 19

Abstract

Abstract In this article, rate coefficients for the reaction of Br atoms with a series of unsaturated species (trichloroethene, k 1; ethene, k 2; acetylene, k 3; and tetrachloroethene, k 4) are reported in 700 Torr air over the temperature range 228–298 K. The data were obtained in a temperature-regulated environmental chamber/FTIR spectrometer system, using standard relative rate techniques, with the reaction of Br with CH 2 O and CH 3 CHO ...