Preparation and chemistry of penta-and hexacoordinated phosphorus compounds containing trifluoroethoxy groups

DB Denney, DZ Denney, PJ Hammond…

Index: Denney,D.B.; Denney,D.Z.; Hammond,P.J. Journal of the American Chemical Society, 1981 , vol. 103, p. 1785

Full Text: HTML

Citation Number: 47

Abstract

Abstract: Tris (trifluoroethy1) phosphite, bis (trifluoroethy1) phenylphosphonite, trifluoroethyl diphenylphosphinite, and triphenylphosphine all react with 2 mol of trifluoroethyl benzenesulfenate to give pentacoordinated phosphorus compounds in which two trifluoroethoxy groups have been added to the original tricoordinated phosphorus compound. When tris (trifluoroethy1) phosphite was allowed to react with 1 mol of ...