Tetrahedron letters

Benzylic oxidation and photooxidation by air in the presence of graphite and cyclohexene

G Sereda, V Rajpara

Index: Sereda, Grigoriy; Rajpara, Vikul Tetrahedron Letters, 2007 , vol. 48, # 19 p. 3417 - 3421

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Citation Number: 11

Abstract

Graphite is introduced as a convenient catalyst for cyclohexene-promoted photooxidation of p-xylene, ethylbenzene, and cumene by air. Availability of the reagent (air), lack of chemical waste, low toxicity, and reusability of the catalyst make the process a good green alternative of oxidation of these industrially important hydrocarbons.