Synthesis and Configuration of the Eight Diastereoisomeric Racemates of Dactyloxene??B. The relative configuration of dactyloxene??B and??C

B Maurer, A Hauser, W Thommen…

Index: Maurer; Hauser; Thommen; et al. Helvetica Chimica Acta, 1980 , vol. 63, # 1 p. 293 - 314

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Citation Number: 9

Abstract

Abstract The eight possible diastereoisomeric racemates of dactyloxene-B have been synthesized by a non-stereoselective route and their configurations and predominant conformations determined by 360-MHz-1 H-NMR. and 90.5-MHz-13 C-NMR. spectroscopy. Natural dactyloxene-B and-C are shown to have the relative configuration rel-(2R, 5R, 9S, 10R) and rel-(2R, 5S, 9S, 10R), respectively.