Absolute configuration and racemization mechanism of arenechalcogenic acids: resolution of tellurinic acid

Y Nakashima, T Shimizu, K Hirabayashi, M Yasui…

Index: Nakashima, Yusuke; Shimizu, Toshio; Hirabayashi, Kazunori; Yasui, Masanori; Nakazato, Masaki; Iwasaki, Fujiko; Kamigata, Nobumasa Tetrahedron Asymmetry, 2004 , vol. 15, # 23 p. 3791 - 3797

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Citation Number: 13

Abstract

An optically active arenetellurinic acid (+)-1d was obtained by means of liquid chromatography on a chiral column. The absolute configuration of the optically active tellurinic acid was assigned by comparing its circular dichroism spectrum with that of an optically active sulfinic acid, the absolute configuration of which was determined by X-ray crystallographic analysis. The absolute configurations of areneseleninic acids, which were ...