Tetrahedron letters

Organometallic reactions in aqueous media with indium

CJ Li, TH Chan

Index: Li, C. J.; Chan, T. H. Tetrahedron Letters, 1991 , vol. 32, # 48 p. 7017 - 7020

Full Text: HTML

Citation Number: 275

Abstract

Abstract Allylation reactions of aldehydes and ketones occurred smoothly with indium metal in aqueous media. Compared to similar reactions with zinc and tin, the reaction with indium proceeds without the need of any promoter. The reaction can be extended to the synthesis of 2-methylene-γ-lactone 6 via the condensation of carbonyl compounds with 2- bromomethylacrylate 4.

~94%

Pd??Catalyzed Nucleophilic Alkylation of Aliphatic Aldehydes...

[Kimura, Masanari; Shimizu, Masamichi; Shibata, Kazufumi; Tazoe, Minoru; Tamaru, Yoshinao Angewandte Chemie - International Edition, 2003 , vol. 42, # 29 p. 3392 - 3395]

One-pot sequential deoximation and allylation reactions of a...

[Lin, Mei-Huey; Lin, Long-Zhi; Chuang, Tsung-Hsun; Liu, Han-Jun Tetrahedron, 2012 , vol. 68, # 12 p. 2630 - 2635]

Tin mediated allylation reactions of enol ethers in water

[Lin, Mei-Huey; Hung, Shiang-Fu; Lin, Long-Zhi; Tsai, Wen-Shing; Chuang, Tsung-Hsun Organic Letters, 2011 , vol. 13, # 2 p. 332 - 335]

Formation of manganese–alkyne complexes mediated by trialkyl...

[Nishikawa, Toshihiro; Shinokubo, Hiroshi; Oshima, Koichiro Tetrahedron, 2003 , vol. 59, # 48 p. 9661 - 9668]

Pd-catalyzed nucleophilic allylic alkylation of aliphatic al...

[Kimura, Masanari; Shimizu, Masamichi; Tanaka, Shuji; Tamaru, Yoshinao Tetrahedron, 2005 , vol. 61, # 15 p. 3709 - 3718]