Synthesis of (±)-lavandulol and its related homoallylic alcohol via allyl transfer from sulphur to tin

Y Ueno, S Aoki, M Okawara

Index: Ueno, Yoshio; Aoki, Seiichi; Okawara, Makoto Journal of the Chemical Society, Chemical Communications, 1980 , # 15 p. 683 - 684

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Citation Number: 20

Abstract

Summary ( & ) -Lavandulol and related homoallylic alcohols were prepared by the stannolysis of allylic sulphones and the subsequent hydroxymethylation of the resulting allylic stannanes with trioxan-BF,.OE&. ... THE synthetic utility of sulphur-stabilized carbanions has been extensively investigated ; their use provides a useful technique for carbon-carbon bond formation.2 Recent developments in this area involve the additional use of transition metal or organometallic ...