A direct route to obtain manganese (III) complexes with a new class of asymmetrical Schiff base ligands

…, A García-Deibe, M Maneiro, J Sanmartín…

Index: Bermejo, Manuel R.; Gonzalez, Ana M.; Fondo, Matilde; Garcia-Deibe, Ana; Maneiro, Marcelino; Sanmartin, Jesus; Hoyos, Olga L.; Watkinson, Michael New Journal of Chemistry, 2000 , vol. 24, # 4 p. 235 - 241

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Citation Number: 49

Abstract

A new class of asymmetrically substituted Schiff base ligands has been synthesised incorporating hard amido donor atoms. The single crystal X-ray structure of one of these ligands, H3-amsal, has been determined [H3-amsal= 3-aza-4-(2-hydroxyphenyl)-N-(2- hydroxyphenyl) but-3-enamide]. The structure reveals the ligand to be suitable for use as an equatorially co-ordinating ligand in octahedral complexes. A new route to obtaining ...