Helvetica Chimica Acta

Die Strukturdynamik von Pentadienylmetall??Verbindungen mit endständiger Alkyl??Gruppe: zugleich «stereoselektive» und «stereodefensive» Synthese eines …

H Bosshardt, M Schlosser

Index: Bosshardt, Herbert; Schlosser, Manfred Helvetica Chimica Acta, 1980 , vol. 63, # 8 p. 2393 - 2403

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Citation Number: 35

Abstract

Summary The (2 Z, 4 E)-,(2 E, 4 Z)-and (2 E, 4 E)-isomers of 2, 4-decadien-1-01 (5) have been obtained with high and predictable stereochemical homogeneity starting from both (2)- and (E)-1, 4-decadiene. These hydrocarbons were hydroxylated in a reaction sequence consisting of metallation (by means of s-butyllithium or butyl-1ithiunVpotassium-t-butoxide, giving rise to organometallic intermediates of specific conformation), dimethoxyborylation ...