The Journal of Organic Chemistry

Heptacyclo [5.5. 1.14, 10.02, 6.03, 11.05, 9.08, 12] tetradecane-13, 14-dione: a novel, polycyclic perpendobiplanar D2d diketone

AP Marchand, AD Earlywine

Index: Marchand, Alan P.; Earlywine, Arthur D. Journal of Organic Chemistry, 1984 , vol. 49, p. 1660 - 1661

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Citation Number: 25

Abstract

(4) Hollowood, MA; McKervey, MA; Hamilton, R.; Rooney, JJ methods. 2 Attempts to functionalize 1 via direct substitution of CH bonds by using electrophilic or free-radical reagents have not been su~ cessful.~ The 13, 14-di-tertbutoxy derivative of 1 (ie, 2) has been synthesized via iron carbonyl promoted cyclodimerization of 7-tert- butoxynorbornadiene? and its structure has been confirmed via single-crystal X-ray ...