Pybox monolithic miniflow reactors for continuous asymmetric cyclopropanation reaction under conventional and supercritical conditions

…, SV Luis, JA Mayoral, V Martinez-Merino…

Index: Cornejo, Alfonso; Fraile, Jose M.; Garcia, Jose I.; Gil, Maria J.; Luis, Santiago V.; Martinez-Merino, Victor; Mayoral, Jose A. Journal of Organic Chemistry, 2005 , vol. 70, # 14 p. 5536 - 5544

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Citation Number: 67

Abstract

Supported catalysts having pybox chiral moieties were prepared as macroporous monolithic miniflow systems. These catalysts are based on styrene-divinylbenzene polymeric backbones having different compositions and pybox chiral moieties. Their corresponding ruthenium complexes were tested for the continuous flow cyclopropanation reaction between styrene and ethyldiazoacetate (EDA) under conventional conditions and in ...