Insertion of carbon monoxide into nickel-alkyl bonds of monoalkyl-and dialkylnickel (II) complexes, NiR (Y) L2 and NiR2L2. Preparation of Ni (COR)(Y) L2 from NiR (Y) …

T Yamamoto, T Kohara, A Yamamoto

Index: Yamamoto, Takakazu; Kohara, Teiji; Yamamoto, Akio Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 7 p. 2161 - 2168

Full Text: HTML

Citation Number: 41

Abstract

Reactions of monoalkylnickel (II) complexes, NiR (Y) L 2 (R= CH 3, C 2 H 5; Y= Cl, suc (succinimido), pht (phthalimido), OC 6 H 4-p-CN; L= 1/2 bpy (2, 2′-bipyridine), PEt 3 (triethylphosphine)), with CO afford monoacylnickel (II) complexes, Ni (COR)(Y) L 2, which are characterized by elemental analysis and spectroscopies (IR and NMR). Reactions of the acylnickel (II) complexes with alcohols and aniline give the corresponding esters and ...