Russian Journal of Physical Chemistry A

The mechanism of the heterogeneous catalytic monooxidation of thiophene derivatives at the S position by hydrogen peroxide

IT Nagieva

Index: Nagieva Russian Journal of Physical Chemistry A, 2009 , vol. 83, # 11 p. 1873 - 1878

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Abstract

Abstract A biomimetic catalytic reaction system for hetero-oriented monooxidation of heteroaromatic compounds was developed experimentally. The system consisted of two interacting synchronous reactions of the decomposition of H 2 O 2 and substrate oxidation. The problem related to the preparation, isolation, and identification of thiophene derivative S- monoxides was solved.