Tetrahedron

Reaction between triphenylphosphine and aromatic amines in the presence of diethyl azodicarboxylate: an efficient synthesis of aryliminophosphoranes under neutral …

M Adib, E Sheikhi, A Deljoush

Index: Adib, Mehdi; Sheikhi, Ehsan; Deljoush, Azadeh Tetrahedron, 2011 , vol. 67, # 22 p. 4137 - 4140

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Citation Number: 9

Abstract

Abstract An efficient synthesis of aryliminophosphoranes is described. A mixture of an aromatic amine, diethyl azodicarboxylate and triphenylphosphine undergo a Mitsonobu type reaction at ambient temperature in dry dichloromethane to afford aryliminophosphoranes in excellent yields.