Elucidation of the vicarious nucleophilic substitution of hydrogen mechanism via studies of competition between substitution of hydrogen, deuterium, and fluorine

M Ma̧kosza, T Lemek, A Kwast…

Index: Mudryk, Boguslav; Makosza, Mieczyslaw Tetrahedron, 1988 , vol. 44, # 1 p. 209 - 214

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Citation Number: 41

Abstract

Relations of rates of the vicarious nucleophilic substitution of hydrogen (VNS) and SNAr substitution of fluorine in 2-fluoronitrobenzenes with chloroalkyl aryl sulfone carbanions were determined from competitive experiments carried out at various concentrations of base.