Spectroscopic studies on the formation of molecular complexes of sulfamethoxazole with novel 2, 3, 5-trichloro-6-alkoxy-1, 4-benzoquinones

K Ganesh, C Balraj, A Satheshkumar…

Index: Ganesh; Balraj; Satheshkumar; Elango Journal of Molecular Structure, 2013 , vol. 1033, p. 312 - 320

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Abstract

UV–Vis, 1H NMR, FT-IR, LC–MS and fluorescence spectral techniques were employed to investigate the mechanism of interaction of sulfamethoxazole with alkoxy substituted 2, 3, 5- trichloro-1, 4-benzoquinones and to characterize the reaction products. The interactions of these quinones with sulfamethoxazole (SULF) were found to proceed through the formation of donor–acceptor complex, containing radical anion and its conversion to the product. ...