Chemistry of N-thiosulfinylanilines. V. Reactions of N-thiosulfinylanilines with nucleophilic reagents.

…, T Hosogai, R Okazaki, N Inamoto

Index: Inagaki, Yoshio; Hosogai, Takeo; Okazaki, Renji; Inamoto, Naoki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 1 p. 205 - 209

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Citation Number: 14

Abstract

2, 4-Di-t-butyl-6-methyl-N-(thiosulfinyl) aniline (1) gave 2, 4-di-t-butyl-6-methylaniline in the reactions with such reagents as alkylamines, thiourea, butyllithium, alkylmagnesium halides, 1-(1-pyrrolidinyl) cyclopentene, and hydrogen sulfide. Triphenylphosphine reacted with 1 to give (2, 4-di-t-butyl-6-methylphenylimino) triphenylphosphorane and bis (2, 4-di-t-butyl-6- methylphenyl) sulfur diimide. Reaction of triphenylphosphine with 2, 4, 6-tri-t-butyl-7, 8- ...