Reaction of the Trichloromethyl Group with Di-and Trialkyl Phosphites

JA Kepler, FI Carroll, RA Garner…

Index: Kepler,J.A. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 105 - 107

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Citation Number: 9

Abstract

This reaction is very similar to that reported by Marks for the alkylation of hexachlorocyclopentadiene with triethyl phosphite to give 1, 2, 3, 4, 5- pentachloroethylcyclopentadiene and probably occurs by a similar mechanism as shown in Scheme III. a This scheme suggests initial attack on halogen to give the anion and [ClP (OC2Hs) a]+. The ion pair will decompose in ethanol to form I1 and triethyl ph~ sphate.~ In ...