Tandem Photoarylation–Photoisomerization of Halothiazoles: Synthesis, Photophysical and Singlet Oxygen Activation Properties of Ethyl 2??Arylthiazole??5?? …

…, S Belviso, M D'Auria, F Lelj, R Racioppi…

Index: Amati, Mario; Belviso, Sandra; D'Auria, Maurizio; Lelj, Francesco; Racioppi, Rocco; Viggiani, Licia European Journal of Organic Chemistry, 2010 , # 18 p. 3416 - 3427

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Citation Number: 3

Abstract

Abstract The photochemical reaction between ethyl 2-chlorothiazole-5-carboxylate and benzene gave no product. In contrast, the reaction with ethyl 2-iodothiazole-5-carboxylate gave ethyl 3-phenylisothiazole-4-carboxylate. The same behaviour was observed if the reaction was performed in the presence of furan, thiophene and 2-bromothiophene. The products thus obtained were studied for their photophysical properties and it was found ...