Journal of the American Chemical Society

Titanium-mediated carbonyl olefinations. 1. Methylenations of carbonyl compounds with dimethyltitanocene

NA Petasis, EI Bzowej

Index: Petasis, Nicos A.; Bzowej, Eugene I. Journal of the American Chemical Society, 1990 , vol. 112, # 17 p. 6392 - 6394

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Citation Number: 529

Abstract

(II) It can be exposed to water during the normal workup procedure or to air during weighing and handling. This reagent can be stored in the dark as a toluene or THF solution for several months without significant decomposition, as indicated by NMR. As a solid, however, this light-sensitive compound decomposes rapidly.