e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Helvetica chimica acta
The adamantane rearrangement of 1, 2??trimethylenenorbornanes. Part V. Rearrangements of 1, 2??trimethylenenorbornanes initiated by regioselective formation of …
AM Klester, C Ganter
Index: Klester, Alfred Michael; Ganter, Camille Helvetica Chimica Acta, 1985 , vol. 68, p. 734 - 744
Abstract The behaviour of the regioselectively generated carbocation centers at C (2) and C (6) in 1, 2-trimethylenenorbornanes was investigated in order to study the occurrence or absence of a degenerate rearrangement E⇄ M in the adamantane rearrangement of both 1, 2-endo-(1) and 1, 2-exo-trimethylenenorbornane (2) to 2-endo, 6-endo- trimethylenenorbornane (3). A degenerate rearrangement E⇄ M is inevitably involved ...