Thermoneutral dyotropic transfer of hydrogen in a hydrocarbon

JP Hagenbuch, B Stampfli, P Vogel

Index: Hagenbuch, Jean-Pierre; Stampfli, Brigitte; Vogel, Pierre Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3934 - 3935

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Citation Number: 20

Abstract

The concerted transfer of two hydrogen atoms from an ethane to an ethylene group in a process suprafacial on both reactants is a thermally “allowed” pericyclic reaction.'The diimide reduction of olefins2 is an example, and analogous reactions with hydrocarbons have also been reported; they are all highly exothermic rocesses involving the formation of aromatic compounds. lJ We report an intramolecular, thermoneutral [, 2,+. 2,+. 2,] ...

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