Abstract Novel organylthio (alkoxy) silanes (I, II, III and XII) and organylthio (diethylamino) silanes (IV, V) are described. They were prepared by treating lithium or lead thiolates with the corresponding chlorosilanes or by cleavage of dimethylbis (diethylamino) silane with thiols. Phenylthiosilanes (Me 3 SiSPh, III and XIII) furthermore can be obtained by reaction of chlorosilanes with benzenethiol in the presence of tertiary amines. The Si S bond of Me ...
