Diiron N-bridged species bearing phthalocyanine ligand catalyzes oxidation of methane, propane and benzene under mild conditions

…, D Bouchu, JMM Millet, AB Sorokin

Index: Zalomaeva, Olga V.; Sorokin, Alexander B. New Journal of Chemistry, 2006 , vol. 30, # 12 p. 1768 - 1773

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Citation Number: 35

Abstract

N-bridged diiron phthalocyanine activates H2O2 to generate a powerful oxidizing species for efficient oxidation of methane at ambient temperature in water which is demonstrated for the first time. Mechanistic features of oxidation of methane and benzene (benzene oxide