Preparation and interconversion of dithiatriazine derivatives: crystal, molecular, and electronic structure of bis (5-phenyl-1, 3, 2, 4, 6-dithiatriazine)(PhCN3S2) 2

…, CL French, RT Oakley, AW Cordes…

Index: Boere, Rene T.; French, Catherine L.; Oakley, Richard T.; Cordes, A. Wallace; Privett, J. Ann James; et al. Journal of the American Chemical Society, 1985 , vol. 107, # 25 p. 7710 - 7717

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Citation Number: 35

Abstract

Abstract: The reaction of N, N, N'-tris (trimethy1silyl) benzamidine with S3N3C13 yields PhCN5S3, a bicyclic 5-phenyl-1, 3, 2, 4, 6-dithiatriazine derivative with an-NSN-unit bridging the 1, 3-sulfur atoms. Oxidation of this compound with chlorine produces 5-phenyl-1, 3- dichloro-1, 3, 2, 4, 6-dithiatriazine (PhCN3S2C12) which, upon reduction with triphenylstibine, affords the dimeric species bis (5-phenyl-1, 3, 2, 4, 6-dithiatriazine)( ...