Beilstein journal of organic chemistry

Gold (I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers

FM Istrate, F Gagosz

Index: Istrate, Florin M.; Gagosz, Fabien Beilstein Journal of Organic Chemistry, 2011 , vol. 7, p. 878 - 885

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Citation Number: 26

Abstract

Abstract A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold (I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions.

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