Rearrangement in the Reaction of α-Halogenonaphthalenes with Lithium Diethylamide

H Gilman, NN Crounse, SP Massie Jr…

Index: Gilman; Nobis Journal of the American Chemical Society, 1945 , vol. 67, p. 1479

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Citation Number: 19

Abstract

&-Biotin has been converted by the Raney nickel hydrogenolysis reaction into dl- desthiobiotin. dl-Allobiotip and dl-epi-allobiotin have been converbd to a common desthio derivative, dl-desthioallobiotin, which differs from dl-desthiobiotin. These desthio derivatives were obtained also by an alternative series of reactions starting with the 3-acetamido-4- benzamidotetr~ hydro-2-thiophenevaleric acid methyl esters which were treated with ...